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Reversible deactivation radical polymerization initiators
Name: Reversible deactivation radical polymerization initiators
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A well controlled RDRP process requires: 1) the reversible deactivation process should be sufficiently fast; 2) the chain breaking reactions which cause the loss of chain end functionalities should be limited; 3) properly maintained radical concentration; 4) the initiator should have proper activity. History and character - Reversible-deactivation - Common features - Examples. In the case of reversible deactivation radical polymerization (RDRP), a majority of chain must be held in a dormant state to ensure that the concentration of active carriers is sufficiently low as to render chain termination reactions negligible. Reversible-deactivation radical polymerization of chloroprene and the synthesis of novel in benzene using 2,2′-azobis(isobutyronitrile) (AIBN) as initiator.
In order to further explore the potential of thiolactone chemistry for the field of reversible-deactivation radical polymerization (RDRP), we have. Dormant polymer. Active polymer radical + capping group activation Absence of irreversible transfer and termination . yl Chlorides used as ATRP Initiators. merizations is “reversible-deactivation radical polymerization”. . Note 1: An initiating species may be formed from an initiator or be the initiator.
Mediation of reversible deactivation radical polymerization (RDRP) by cobalt(II) complexes . cobalt(II) complex, a thermo-initiator such as AIBN or V deactivation radical polymerization (RDRP) using multi-objective atom) catalyzes the homolytic cleavage of an ATRP initiator (R0X') to yield. This article is a Perspective that introduces several review articles in the field of reversible-deactivation radical polymerizations (RDRPs), also known as living/.